环境与发展

无机陶瓷膜在油水分离中的研究进展

石 菁煊

福州大学至诚学院环境资源工程系

刘 菁伟

福州大学至诚学院环境资源工程系

陈 琪

福州大学至诚学院环境资源工程系

熊 赛赛

福州大学至诚学院环境资源工程系

李 胜欣

福州大学至诚学院环境资源工程系

DOI: https://doi.org/10.59429/hjfz.v5i4.1297

Keywords: 陶瓷膜；含油废水；膜改性；膜污染

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Abstract

陶瓷膜以其机械强度高、耐有机溶剂性好、良好的化学稳定性、耐污性强、寿命长、良好的除污能力等诸多优点， 在油水分离领域受到了众多科研者的广泛关注。根据近年来陶瓷膜在油水分离方面的研究现状，介绍 SiO2、TiO2、AlO2、Zr O2 及其他等材料的陶瓷膜近年来的发展，以及陶瓷膜的清洗、污染问题，并介绍新型组合工艺如何用来解决膜污染问题。

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References

[1]徐昆鹏.含油废水处理方法的研究现状及展望[J].化工

管理,2021(24):21-22.DOI:10.19900/j.cnki.ISSN1008-4800.202

1.24.011. [2]解宏端,刑文东,杨雨桐,王玲.含油废水处理技术现状

及发展趋势[J].科技资讯,2015,13(18):137-139.DOI:10.16661/j. cnki.1672-3791.2015.18.076. [3]Hu Y , Zhu Y , Wang H , et al. Facile preparation

of superhydrophobic metal foam for durable and high effi cient continuous oil-water separation[J]. Chemical Engineeri ng Journal, 2017, 322:157-166. [4]Yan L，Hong S，Li M L，et al．Application of th

e Al2O3-PVDF nano composite tubular ultrafiltration ( UF ) membrane for oily wastewater treatment and its antifoulin

g research［J］．Separation and Purification Technology，20

09，66( 2) : 347－352．

[5]Chakrabarty B，Ghoshal A K，Purkait M K．Ultraf

iltration of stable oil-in-water emulsion by polysulfone me mbrane［J］． Journal of Membrane Science，2008，325( 1)

: 427－437．

[6]R.R. Bhave, Inorganic membranes synthesis, charact eristics and applications, Van Nostrand Reinhold, New York, 1991. [7]YANG C，ZHANG G S，XU N P，et al. Preparati on and application in oil-water separation of ZrO2/α-Al2O

3 MF membrane［J］. Journal of Membrane Science，1998，

142（2）：235-243. [8]潘艳秋，王文娟，王婷婷，等．基于油水分离的陶瓷

膜基双层复合动态膜的制备和应用［J］．天津大学学报( 自

然科学与工程技术版) ，2015，48( 3) : 269－274．

[9]MAＲZOUK S S，NADDEO V，BANAT F，et al．

Preparation of TiO2 / SiO2 ceramic membranes via dip co

ating for the treatment of produced water［J］．Chemospher e，2021，273: 129684．

[10]ESHAM M I M, AHMAD A L, OTHMAN M H

D. Fabrication, optimization, and performance of a tio2 coa

ted bentonite membrane for produced water treatment: effec

t of grafting Time [J].Membranes,2021,11(10). [11]张运鸽. 用于含油废水净化的 TiO_2 光催化复合材

料的研究[D].天津大学,2015.

[12]王艳，马百文，乌布利希特·马蒂亚斯，董英超，

赵旭.氧化铝陶瓷膜在水净化中的研究进展与展望[J].水研究，

2022，226. [13]Xianfu Chen,Wei Zhang,Yuqing Lin,Yuanyuan Cai, Minghui Qiu,Yiqun Fan. Preparation of high-flux γ-alumin

a nanofiltration membranes by using a modified sol–gel m

ethod[J]. Microporous and Mesoporous Materials,2015,214. [14]Sofiatun Anisah,Masakoto Kanezashi,Hiroki Nagasa wa,Toshinori Tsuru. Al 2 O 3 nanofiltration membranes fab

ricated from nanofiber sols: Preparation, characterization, an

d performance[J]. Journal of Membrane Science,2020,611(pr epublish). [15]Raji Yusuf Olabode,Othman Mohd Hafiz Dzarfan,S

apiaa Md Nordin Nik Abdul Hadi,Adam Mohd Ridhwan,M

ohd Said Khairul Anwar,Ismail Ahmed Fauzi,Rahman Mukh

lis A.,Jaafar Juhana,Farag Twibi Mohamed,Alftessi Sabeer Abdulhamid. Synthesis and characterization of superoleopho

bic fumed alumina nanocomposite coated via the sol-gel pr ocess onto ceramic-based hollow fibre membrane for oil-wa

ter separation[J]. Ceramics International,2021,47(18). [16]杨斌,吴文标,黄威.二氧化硅制备超滤和纳滤膜的研

究进展[J].食品工业科技,2010,31(12):397-400.DOI:10.13386/j. issn1002-0306.2010.12.086. [17]周耀，陈永英，迟玉兰，等.溶胶-凝胶法制备的 Si

O2,膜的结构与性质[J].无机材料学报，1994.9(4):429-436

[18]李莎. 凝胶注模成型制备多孔SiO_2陶瓷[D].天津大

学,2010. [19]杨勇法. 氧化物平板陶瓷膜的制备及性能研究[D]. 湖南大学,2017. [20]Xu Ligang,Wang Yali,Li Qunyan,Cui Suping,Tang

Mingxue,Nie Zuoren,Wei Qi. A Methyl-Modified Silica Lay

er Supported on Porous Ceramic Membranes for the Enhan

ced Separation of Methyl Tert-Butyl Ether from Aqueous S

olution[J]. Membranes,2022,12(5). [21]YUAN L, WEN T, JIANG L, et al. Modified sup

erhydrophilic/ underwater superoleophobic mullite fiber-base d porous ceramic for oil-water separation[J]. Materials Rese

arch Bulletin, 2021, 143: 111454. [22]赵志育,钟林新,王栋,董应超.铜污泥基中空纤维尖晶

石膜的制备及油水分离性能[J].膜科学与技术,2022,42(02):1- 7.DOI:10.16159/j.cnki.issn1007-8924.2022.02.001. [23]Aba N F D，Chong J Y，Wang Bo，et al. Graph

ene oxide membranes on ceramic hollow fibers-microstructu

ral stability and nanofiltration performance［J］. Journal of

Membrane Science，2015，484：87-94

[24]Fan X , Zhao H , Liu Y , et al. Enhanced perme

ability, selectivity, and antifouling ability of CNTs/Al2O3 m

embrane under electrochemical assistance.[J]. Environmental

Science & Technology, 2015, 49(4). [25] Li P , Yang C , Sun F , et al. Fabrication of co

nductive ceramic membranes for electrically assisted fouling

control during membrane filtration for wastewater treatmen

t[J]. Chemosphere, 2021, 280(318):130794.